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Topic: NMR interpretations  (Read 5831 times)

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Offline ngray

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NMR interpretations
« on: October 02, 2008, 04:24:52 PM »
What is the common CDCl3 peak/signal for 19F NMR?

Offline azmanam

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Re: NMR interpretations
« Reply #1 on: October 02, 2008, 04:41:58 PM »
There's no F in CDCl3 - no 19F signal.
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Offline nielsgeode

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Re: NMR interpretations
« Reply #2 on: October 04, 2008, 05:42:34 AM »
There's no F in CDCl3 - no 19F signal.

exactly  ;D

for 1H it's @ 7.24
for 13C it's @ 78.00 (the central peak)
for 35Cl / 37Cl ==> cannot really be measured by NMR. I tried it once on a Varian 500MHz but it just gives crap

Offline sjb

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Re: NMR interpretations
« Reply #3 on: October 04, 2008, 07:37:49 AM »
There's no F in CDCl3 - no 19F signal.

exactly  ;D

for 1H it's @ 7.24
for 13C it's @ 78.00 (the central peak)
for 35Cl / 37Cl ==> cannot really be measured by NMR. I tried it once on a Varian 500MHz but it just gives crap

Have you got a reference for that? I've always used 7.27 and 77.1  (for proton and carbon respectively). I do know that it's all relative though - so as long it's clear what you reference to, it's all much of a muchness in the end.

S

Offline muse

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Re: NMR interpretations
« Reply #4 on: October 15, 2008, 02:47:00 PM »
Hi

This article is very usefull for shift references and impurities in NMR samples.
http://ccc.chem.pitt.edu/wipf/Web/4505.pdf

-m

Offline macman104

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Re: NMR interpretations
« Reply #5 on: October 15, 2008, 03:00:12 PM »
It also depends how accurately your shift reference is set to 0 (if you're using TMS).

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