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Topic: reaction mechanism problems  (Read 5096 times)

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Offline philos

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reaction mechanism problems
« on: December 10, 2008, 03:17:07 PM »
For my organic chem class we were given a small project of trying to find out the mechanism for several different things. I have been working on this for the last 2 weeks and have not gotten anywhere yet.

Any help would be great, and not sure if i am allowed to give that person money via paypal if they can solve the entire problem for me...

thanks

Offline azmanam

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Re: reaction mechanism problems
« Reply #1 on: December 10, 2008, 05:16:57 PM »
show us what you've got so far and we'll help you through.

first (and most important) hint:  for each reaction, label the nucleophile.  label the electrophile.  nucleophiles attack electrophiles.  repeat.
Knowing why you got a question wrong is better than knowing that you got a question right.

Offline philos

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Re: reaction mechanism problems
« Reply #2 on: December 10, 2008, 06:02:25 PM »
Theres actually another 6 problems which I was able to get, these ones ive posted im totally lost on.

Offline philos

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Re: reaction mechanism problems
« Reply #3 on: December 10, 2008, 07:15:09 PM »
I was actually able to kinda workout the last 2 attachments, the ones with the boxes.

They wernt that bad once i was able to find some other examples online that were similar.

BUT i still havnt gotten the first part with the two mechanisms.

Offline sjb

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Re: reaction mechanism problems
« Reply #4 on: December 11, 2008, 09:34:47 AM »
I was actually able to kinda workout the last 2 attachments, the ones with the boxes.

They wernt that bad once i was able to find some other examples online that were similar.

BUT i still havnt gotten the first part with the two mechanisms.

OK, for part 1 what does bromine do to double bonds?

For part 2 what's the nature of your reactants?


Offline ryllvn

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Re: reaction mechanism problems
« Reply #5 on: December 19, 2008, 03:54:56 PM »
+ problem 1 :
U can understand like  the reaction react following Ae mechanism:
Br+--Br- attach  CH=CH to form CHBr-CH+ and this cationic was stable by Oxgen 
after that's the OH attach by intramolecular cyclization reaction. done
+problem 2 :
that's not very difficult. firstly, starting metarial is 1-methylcyclohexane, second, 1-bromo-1-methylcyclohexan, following, 1-methylcyclohex-1-ene, heptan-2,7-dion. done
P.3:
so easy, ====>1- butene , then ,  1,2-dibromobutane, then== buta-1-ine and hexa-3-ine , then hexene-3, then hexa-3,4-diol. done

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