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Offline manjui

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Chemistry Homework
« on: April 22, 2009, 11:42:27 AM »
Hello, could someone help me with some homework and explain this to me?

"If the atmospheric pressure is 0.960 atm in a manometer, what is the pressure of the enclosed gas if the if the liquid is mercury and has a hight of 10.3 cm?"
I know I have to keep all the units the same...here's what I am doing, please let me know where I am going wrong!  :-[

I convert 10.3 cm to mm (103 mm) and 0.960 atm to mm Hg (729.6 mm Hg) then I add the two together and get 832.6 mm Hg and convert that to atm: 1.095 atm. But I know that's not the right answer!



Offline ARGOS++

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Re: Chemistry Homework
« Reply #1 on: April 22, 2009, 12:01:55 PM »

Dear manjui;

Which side of the manometer shows you the higher mercury level?:
            http://en.wikipedia.org/wiki/Pressure_measurement#Liquid_column 

Good Luck!
                    ARGOS++

Offline manjui

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Re: Chemistry Homework
« Reply #2 on: April 22, 2009, 12:03:08 PM »
The right side. I also forgot to mention that it has a closed end.

Offline ARGOS++

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Re: Chemistry Homework
« Reply #3 on: April 22, 2009, 12:11:25 PM »

Dear manjui;

In this case:  Which side is closed and on which side is the unknown pressure applied?

Good Luck!
                    ARGOS++

Offline manjui

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Offline ARGOS++

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Re: Chemistry Homework
« Reply #5 on: April 22, 2009, 12:26:57 PM »

Dear manjui;

The right most picture makes only sense, if the pressure above the mercury on the right side is equal zero (p0 = 0 mm Hg).

So calculate from the balance:  pleft + pright = 0.

Good Luck!
                    ARGOS++

Offline manjui

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Re: Chemistry Homework
« Reply #6 on: April 22, 2009, 12:34:09 PM »
The right most picture (iii) is the one I need help with. If the atmospheric pressure is 0.960 atm, what is the pressure of the enclosed gas in sample (iii)?

Offline ARGOS++

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Re: Chemistry Homework
« Reply #7 on: April 22, 2009, 12:40:21 PM »

Dear manjui;

Yes I know that!
But what is the "total" pressure on the right side of this manometer (iii)?

Good Luck!
                    ARGOS++

Offline manjui

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Re: Chemistry Homework
« Reply #8 on: April 22, 2009, 12:46:37 PM »
I have no idea. All it says is: "if the atmospheric pressure is 0.960 atm, what is the pressure of the enclosed gas of (iii)?"

Offline ARGOS++

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Re: Chemistry Homework
« Reply #9 on: April 22, 2009, 12:58:40 PM »

Dear manjui;

In picture (iii) the surrounding pressure has no effect, as I told you, and according to:
     http://www.chm.davidson.edu/Chemistryapplets/GasLaws/Pressure.html  

So the pressure on the right side is: pright = p0  + pHg with p0 = 0 mm.

And as the sample pressure must be equal pright,  so pleft = ?

Good Luck!
                    ARGOS++

Offline manjui

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Re: Chemistry Homework
« Reply #10 on: April 22, 2009, 01:01:02 PM »
I'm sorry but that makes no sense.  :-[

Offline ARGOS++

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Re: Chemistry Homework
« Reply #11 on: April 22, 2009, 01:08:02 PM »

Dear manjui;

NO - that makes very much sense!

It follows from: http://www.chm.davidson.edu/Chemistryapplets/GasLaws/Pressure.html 

              --  that simply: pSample = pHg!

You may study the given link once more and very carefully!

Good Luck!
                    ARGOS++

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