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Topic: peak heights in carbon-13 nmr specta  (Read 15091 times)

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Offline robert_l

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peak heights in carbon-13 nmr specta
« on: May 06, 2009, 09:31:33 AM »
hello,

please could someone explain the significance of the peak heights in carbon-13 nmr spectra? i read that there are not simple explanations, but if possible, please keep it simple.

i've got a coursework question telling me to comment on why a peak is smaller than another.

so, in what circumstance is peak height affected?

thanks in advance.

Offline nj_bartel

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Re: peak heights in carbon-13 nmr specta
« Reply #1 on: May 06, 2009, 12:29:48 PM »
I'm pretty sure higher peak = more attached hydrogens

Offline ARGOS++

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Re: peak heights in carbon-13 nmr specta
« Reply #2 on: May 06, 2009, 12:57:57 PM »

Dear nj_bartel;

According to my reference (in German) it is not true that the signal intensities correlate with the number of attached hydrogens.  Otherwise you would not see some carbons of polyaromatic compounds!

The reference tells that it more correlates with the number of carbons (similar to hydrogen in 1H), but much less accurate, and with a lot of exceptions.

Sorry I don’t own more relevant info about.
Good Luck!
                    ARGOS++

Offline robert_l

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Re: peak heights in carbon-13 nmr specta
« Reply #3 on: May 08, 2009, 02:01:42 AM »
Many thanks.

Offline rita87

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Re: peak heights in carbon-13 nmr specta
« Reply #4 on: May 09, 2009, 08:49:48 AM »
I agree with nj_bartel.  I have a few literatures telling that peak height depends on Hydrogen atoms. It doesn't mean that Carbon without Hydrogen has no peak, It means that Carbon with no Hydrogen is smaller than those with Hydrogen attached to them.

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