April 27, 2024, 06:39:41 PM
Forum Rules: Read This Before Posting


Topic: Arrhenius Equation?  (Read 5312 times)

0 Members and 1 Guest are viewing this topic.

Offline moonlitbubbles

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +0/-0
Arrhenius Equation?
« on: July 19, 2009, 02:36:33 AM »
The activation energy of an uncatalyzed reaction is 94 kj/mol . The addition of a catalyst lowers the activation energy to 52 kj/mol.  Assuming that the collision factor remains the same, by what factor will the catalyst increase the rate of the reaction at 24 C?

Will someone please show me (in steps) how to solve this, and whether or not it is with the Arrhenius Equation.  Thanks!
 

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27665
  • Mole Snacks: +1801/-410
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Arrhenius Equation?
« Reply #1 on: July 19, 2009, 04:33:25 AM »
Direct application of Arrhenius equation. Just plug in numbers.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline moonlitbubbles

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +0/-0
Re: Arrhenius Equation?
« Reply #2 on: July 19, 2009, 03:25:47 PM »
That is the problem.  I used the Arrhenius equation and got 7.01 x 10^-10.  But the answer is 2.4 x 10^7.  I don't understand how they got that answer.  That is why I really need this equation worked out step by step.  I am not that great at chemistry, or math.  But I have done this over and over, and I keep getting the same numbers.  I have the activation energy = 52kj/mol (52,000 J/mol-K), R = 8.314 T= 294K.  I multiplied R x T.  Divided -52,000 J by R x T.  Then took e^x of that answer.  What am I doing wrong???

Offline Yggdrasil

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 3215
  • Mole Snacks: +485/-21
  • Gender: Male
  • Physical Biochemist
Re: Arrhenius Equation?
« Reply #3 on: July 19, 2009, 05:50:13 PM »
You're supposed to compare the rate of the uncatalyzed reaction (Ea = 94 kJ/mol) and the catalyzed reaction (Ea = 52 kJ/mol).  So, you're halfway to the answer.

Sponsored Links