Do you know how to find the isomers? if yeah your on the right path!..let me know, it's very easy i can help you.
well constitutional isomers..is the kind of the isomer that is writen with line, well im not able to explain it with the right terminolgy, so please use google image so you can see constitutional isomers and understand it, it really helps!
well since you know the nomenclatures so draw them..
well regarding the 2nd part you have to write the condensed structure
here for the octane you wrote..
CH3-CH2-CH2-CH2-CH2-Ch2-CH2-CH3
well here you have to make more condensed if you can
like CH3-(CH2)
6-CH3...so yeah your on the right path so go on.
moreover,
Does five of the octanes mean 5 of 18 structural isomers of octane?
, yeah you're right!
Good Luck.