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Topic: 9.73g of lead (IV) chloride contains..  (Read 10615 times)

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Offline alwaysanewb

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9.73g of lead (IV) chloride contains..
« on: September 06, 2009, 08:48:35 PM »
9.73g of lead (IV) chloride contains enough CL- ions to make___g of magnesium chloride.
Can someone walk me through this? I've been away from chem for awhile.

Offline UG

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Re: 9.73g of lead (IV) chloride contains..
« Reply #1 on: September 06, 2009, 10:44:42 PM »
Calculate the number of moles of PbCl4. This is done by dividing the mass by the molar mass.
One mole of PbCl4 has 4 moles of chloride ions, so you can work out how many moles of chloride ions there are. Every two chloride ions will combine with one magnesium ion to form MgCl2. The mass of MgCl2 is calculated by multiplying the number of moles of magnesium ions needed (since the mole ratio MgCl2:Mg is 1:1 whereas MgCl2:Cl- is 1:2) to react with the chloride ions by the molar mass of magnesium chloride.

Offline alwaysanewb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #2 on: September 16, 2009, 04:21:00 PM »
Okay,
Calculated that there are 0.0278 moles of PbCl4 in 9.73 grams of PbCl4.
What next?

Offline Borek

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Re: 9.73g of lead (IV) chloride contains..
« Reply #3 on: September 16, 2009, 04:22:34 PM »
What next?

Most likely you should read next phrase of the UG post.
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Offline alwaysanewb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #4 on: September 17, 2009, 12:18:46 AM »
What next?

Most likely you should read next phrase of the UG post.

I wish I could relate to your sarcasm. I'm sourly unsure of how to do the next step.
If you can help then post.  Please don't waste my time.

Offline alwaysanewb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #5 on: September 17, 2009, 02:19:16 AM »
Okay,
Calculated that there are 0.0278 moles of PbCl4 in 9.73 grams of PbCl4.
Then,
Found percent composition of Cl in PbCl4 which is 40.6%.
Took 40.6% of 0.0278g which is 0.0113g.
So I assume that 0.0113g is the amount of Cl moles in 0.0278 moles of PbCl4???

Offline sjb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #6 on: September 17, 2009, 03:33:41 AM »
Okay,
Calculated that there are 0.0278 moles of PbCl4 in 9.73 grams of PbCl4.
Then,
Found percent composition of Cl in PbCl4 which is 40.6%.

So far, so good

Took 40.6% of 0.0278g which is 0.0113g.
So I assume that 0.0113g is the amount of Cl moles in 0.0278 moles of PbCl4???

Where has the 0.0278g come from?

Offline alwaysanewb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #7 on: September 17, 2009, 03:47:13 AM »
the 0.0278g came from 9.73g / 349.0230

moles= mass/molar mass

Offline Borek

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Re: 9.73g of lead (IV) chloride contains..
« Reply #8 on: September 17, 2009, 04:12:53 AM »
Seems like you have no idea what mole is :(

You are calculating number of moles and write that result is a mass. It is not.

the 0.0278g came from 9.73g / 349.0230

moles= mass/molar mass

It is not 9.73g/349.023 - you should list all units. You would get 9.73g/349.023(g/mol) and the result would be 0.0278 mole, not 0.278 g.

Mole is just an overgown dozen - instead of having 12 elements like dozen has, mole has 6.02*1023 elements.

If there are 0.0278 moles of PbCl4, how many atoms of Pb? How many atoms of Cl? Knowing how many atoms of Cl in the sample, can you calculate number of moles of chlorine?
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Offline alwaysanewb

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Re: 9.73g of lead (IV) chloride contains..
« Reply #9 on: September 17, 2009, 04:36:26 AM »



I found that there are 0.0028 moles of Cl in 9.73g of PbCl4.
Is this correct?  ???
I calculated this using algebraic ratio and %

Offline Borek

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Re: 9.73g of lead (IV) chloride contains..
« Reply #10 on: September 17, 2009, 04:55:38 AM »
No, it is wrong. You don't need % to calculate it.

How many PbCl4 molecules in one mole?

How many chlorine atoms in PbCl4 molecule?

How many Cl atoms in one mole of PbCl4?

How many moles of Cl in one mole of PbCl4?
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