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Topic: trans and cis  (Read 15981 times)

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arnyk

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Re:trans and cis
« Reply #15 on: June 19, 2005, 05:49:17 PM »
The easiest way to look at cis and trans is this:

(the "_" represents a double bond)

cis - on both sides of the double bond, the carbons branch off the same side.  

\ _ / (both branch upwards) or
  _
/   \ (they both branch downwards)

trans- on both sides of the double bond, the carbons branch off opposite sides.

\ _
    \ (the left branches up, the right branches down)

  _ /
/      (the left branchs down, the right branches up)

Hmm, lol that actually didn't turn out too bad, hopefully you see it with as much clarity as I do. ;)
« Last Edit: June 19, 2005, 05:49:47 PM by arnyk »

Offline hmx9123

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Re:trans and cis
« Reply #16 on: June 20, 2005, 04:40:39 AM »
You also need to remember that in e and g you've got more than cyclooctene--whenever you've got a double bond in a cyclic hydrocarbon, you can't have a trans- isomer until you get over 8 carbons.  The reason that you can't see the isomers in e and g is because it's not drawn in 3D as someone mentioned before.  Take a look through your book and look for trans-cyclooctene.  It's an amazing picture for a simple line drawing.  It will give you a whole new appreciation for drawing with lines.

Offline Winga

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Re:trans and cis
« Reply #17 on: June 20, 2005, 05:21:47 AM »
Ar...I see! :P

Q.(g) is quite tricky!

Offline rleung

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Re:trans and cis
« Reply #18 on: June 20, 2005, 01:59:15 PM »
Thanks for the *delete me* :)

Yea, I am actually reading my Orgo book myself without taking a class.  I am taking Orgo this fall, but I wanted to read the book before school starts so that I have a little understanding going into the class.  

I am using Organic Chemistry by Wade.  Has anyone ever used that book?  If yes, is it good?  The reviews on Amazon were good, but those can be biased sometimes.

Anyway, thanks for the help.  I am sure I will have many more questions this summer as I attempt to self-teach myself Orgo.

Ryan

Ester

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Re:trans and cis
« Reply #19 on: July 04, 2005, 11:24:14 AM »
The easiest way to look at cis and trans is this:

(the "_" represents a double bond)

cis - on both sides of the double bond, the carbons branch off the same side.  

\ _ / (both branch upwards) or
  _
/   \ (they both branch downwards)

trans- on both sides of the double bond, the carbons branch off opposite sides.

\ _
    \ (the left branches up, the right branches down)

  _ /
/      (the left branchs down, the right branches up)

Hmm, lol that actually didn't turn out too bad, hopefully you see it with as much clarity as I do. ;)

This is the most simplified and might i say EASIEST way i have ever saw Cis & Trans being explianed. ;)

arnyk

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Re:trans and cis
« Reply #20 on: July 04, 2005, 06:25:41 PM »
Hah!  It only took me 5 hours and 16 edits to work out the kinks.  :D

Offline hmx9123

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Re:trans and cis
« Reply #21 on: July 06, 2005, 02:57:18 AM »
I actually used the Wade book myself when going through, although it was the 3rd Ed.  Personally, I found it the most readable and best organized organic chemistry book I've ever found.  I've seen Solomons, Morrison & Boyd, Vollhardt, and a number of the other 'big ones'.  Although I find it to be very understandable, it does lack a bit of information that some of the others cover, so some professors prefer not to use it.  I tend to think it's not as much of a problem since a. the professor can cover whatever he or she wants in class regardless of its inclusion in the book and b. it simply lacks certain information, it does not dumb down information and make it incorrect.  I hate it when books don't go into extreme detail and actually present incorrect information because the material was 'dumbed down'.

Offline rleung

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Re:trans and cis
« Reply #22 on: July 06, 2005, 07:04:30 PM »
Thanks so much for the help :)  I finally get it.  

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