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Topic: Which are favored at equilibrium?  (Read 26181 times)

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Offline hiswifetheirmom

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Which are favored at equilibrium?
« on: November 18, 2009, 09:31:04 PM »
Here are my 2 equations. Please tell me whether the reactants or products will be favored at equilibrium. I *think* I know the answers, but I want to double check. Thank you!!

1) HF + OH- ⇌ F- + H2O

2) HCN + OH- ⇌ CN- + H2O

Offline nj_bartel

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Re: Which are favored at equilibrium?
« Reply #1 on: November 18, 2009, 11:37:47 PM »
what do you think and why

Offline orgoclear

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Re: Which are favored at equilibrium?
« Reply #2 on: November 19, 2009, 08:31:07 AM »
Remember that side of the reaction is favoured in equilibrium which has weaker acid and weaker base..

On basis of this heres the first one

(1) HF + OH-  <->  F- + H2O

HF is stronger acid than H2O
OH- is stronger base than F-

So the equilibrium favours the products side here

Now can you try the second one?

Offline hiswifetheirmom

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Re: Which are favored at equilibrium?
« Reply #3 on: November 19, 2009, 09:08:34 AM »
HCN + OH- <---> CN- + H2O

Given the reasoning I would say that in this equation, the products would be more favorable because OH- is the stronger base and HCN is the stronger acid.  Am I right??  :)

Offline orgoclear

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Re: Which are favored at equilibrium?
« Reply #4 on: November 19, 2009, 09:11:52 AM »
Yes  :)

Offline hiswifetheirmom

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Re: Which are favored at equilibrium?
« Reply #5 on: November 19, 2009, 09:13:53 AM »
Yay!!  Thanks so much for your help.  I feel like I truly understand now.  I appreciate it.  :)

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