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Topic: I need help with this Kc problem?  (Read 10068 times)

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Offline Maureen

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I need help with this Kc problem?
« on: December 09, 2009, 09:13:37 PM »

I need help determining the size of Kc ? please explain too!!?


Consider the reaction shown. Using your knowledge of relative acid-base strengths and equilibrium, determine what you can about the size of Kc for the reaction.

H2SeO3(aq) + HSO3-(aq) <=> HSeO3-(aq) + H2SO3(aq)



why is Kc <1 ? how do you know that?

Offline savy2020

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Re: I need help with this Kc problem?
« Reply #1 on: December 10, 2009, 01:39:17 AM »
As you go down a group, the acidic strength of oxyacids decreases. So that means H2SeO3 is weaker than H2SO4. Thus the above reaction as written is non-spontaneous (The reverse reaction is spontaneous).
 :delta:(G0rxn)> 0
So from relation between Kc and  :delta:(G0rxn) you get Kc<1
:-) SKS

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