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Topic: Energy level spacing in a 1D box - spectroscopy  (Read 6739 times)

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Offline AforC

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Energy level spacing in a 1D box - spectroscopy
« on: January 05, 2010, 03:43:45 AM »
Hello

I would be really grateful if somebody could help me with the question below, I really don't know where to start.

Calculate the spacing between the energy levels with n=5 and n= 6 of an electron in a 1D
box of length 5 nm.

Thank you

Offline rajan

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Re: Energy level spacing in a 1D box - spectroscopy
« Reply #1 on: January 07, 2010, 01:58:03 AM »
google "particle in a box" then come back with what you've found.

Offline AforC

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Re: Energy level spacing in a 1D box - spectroscopy
« Reply #2 on: January 17, 2010, 03:50:53 PM »
I have checked on Wikipedia and found some useful equations.
thanks

Offline AforC

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Re: Energy level spacing in a 1D box - spectroscopy
« Reply #3 on: April 07, 2010, 06:09:00 PM »
The energy for each quantum number n,  in a 1D box can be calculated using the equation below

E = (n h^2)/8 m L

Where h is Planck's constant
m is the mass of the particle
and L is the length of the box

The energy difference between two energy levels is then found using:

 :delta: E = ((h^2)/ 8 m L)(2n +1)

the lowest n value is used in the above calculation.

Sorry for writing out the equations but I don't really know how to insert an image!!!

Offline Juan R.

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Re: Energy level spacing in a 1D box - spectroscopy
« Reply #4 on: April 08, 2010, 03:42:04 PM »
The energy for each quantum number n,  in a 1D box can be calculated using the equation below

E = (n h^2)/8 m L

Where h is Planck's constant
m is the mass of the particle
and L is the length of the box

The energy difference between two energy levels is then found using:

 :delta: E = ((h^2)/ 8 m L)(2n +1)

the lowest n value is used in the above calculation.


It is

E = (n^2 h^2) / (8 m L^2)

:delta: E = (2n + 1) (h^2) / (8 m L^2)
The first canonical scientist.

Offline AforC

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Re: Energy level spacing in a 1D box - spectroscopy
« Reply #5 on: April 13, 2010, 02:09:11 PM »
yup my mistake!

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