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Topic: Chemical Kinetics  (Read 7679 times)

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Offline matsci0000

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Chemical Kinetics
« on: January 09, 2010, 11:45:07 AM »
The following data are obtained for the initial rates of then reaction for A+2B+C----->2D+E
Experiment..[A]....[C]..Initial rate
1                   1.40     1.40     1.00        R1
2                   0.70     1.40     1.00        R2=(R1)/2
3                   0.70     0.70     1.00       R3=(R2)/4
4                   1.40     1.40      0.50      R4=16R3
5                   0.70      0.70      0.50      R5=?
a)What is the order of the reaction with respect to A,B,C?
b)What is the value of R5 in terms of R1.
« Last Edit: January 09, 2010, 12:38:14 PM by matsci0000 »

Offline matsci0000

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My answer
« Reply #1 on: January 09, 2010, 11:47:43 AM »
Middle row indicates the concentrations of B.

I got the orders 1,2,and -4 respectively.
Can any one just verify?? :-\

Offline Schrödinger

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Re: Chemical Kinetics
« Reply #2 on: January 09, 2010, 11:56:05 AM »
Are you sure the data for experiment 4 is correct?
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Offline matsci0000

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Re: Chemical Kinetics
« Reply #3 on: January 09, 2010, 12:39:52 PM »
Yes,there was an error in the data of experiment 4 .I've corrected this error.

Offline sjb

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Re: Chemical Kinetics
« Reply #4 on: January 09, 2010, 01:44:11 PM »
Can you write the rate of experiment 4 in terms of the rate of experiment 1?

Then you can see what happens when you half each of the rates in turn, and so apply to R5

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