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Topic: Zinc powder/dust  (Read 4534 times)

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Offline OrthoParaDirector

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Zinc powder/dust
« on: February 09, 2010, 01:34:00 PM »
Hello,

What is the general use of zinc powder/dust in solutions?

Does it act as a reducer? if yes why not use another reducer Fe2+for example?

Thanks.

Offline sjb

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Re: Zinc powder/dust
« Reply #1 on: February 09, 2010, 02:11:28 PM »
Zinc metal can act as a reductant, yes; but there are other things it can do too, see e.g, Reformatsky chemistry. Sometimes it can act as a selective reductant, when things like Fe(II) would either be too slow, or react with more than one functionality

Offline OrthoParaDirector

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Re: Zinc powder/dust
« Reply #2 on: February 09, 2010, 02:49:17 PM »
I think in my case it could act as a selective reductant. What compounds does zinc powder/dust selectively reduce?

Thanks

Offline sjb

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Re: Zinc powder/dust
« Reply #3 on: February 26, 2010, 05:34:35 PM »
I've only ever used it as a reductant for nitro groups, either all the way down to the amine, or in a couple of cases down to the hydroxyamine. Typical functional groups it has tolerated here include halogens, alkenes and nitriles.

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