Hello!
I'm working on solubility and how pH affects a solution. Surfing the world wide web for information, I came upon this example, which was using something called K
sum. Which is nothing I have ever known about, and the example looked like this:
(1) CaCO
3(s)
Ca
2+(aq) + CO
32–(aq) K
sp(CaCO
3)=3.36x10
–9(2) CO
32–(aq) + H
3O
+(aq)
HCO
3–(aq) + H
2O(l) 1/K
a2(H
2CO
3)=1/4.7x10
–11Sum CaCO
3(s) + H
3O
+(aq)
Ca
2+(aq) + HCO
3–(aq) + H
2O(l) K
sumK
sum = K
sp(CaCO
2)/K
a(HCO
3–) = 3.36×10
–9 / 4.7×10
–11 = 71.5.
I understand the summation of the reactions, but I do not understand K
sum, what it is and why it is division and not addition...
Can anyone please explain this to me?