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Topic: Ksum?  (Read 1757 times)

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Offline Kritkatten

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Ksum?
« on: February 20, 2010, 01:57:08 PM »
Hello!
I'm working on solubility and how pH affects a solution. Surfing the world wide web for information, I came upon this example, which was using something called Ksum. Which is nothing I have ever known about, and the example looked like this:

(1)    CaCO3(s)  ::equil:: Ca2+(aq) + CO32–(aq)   Ksp(CaCO3)=3.36x10–9
(2)    CO32–(aq) + H3O+(aq)  ::equil:: HCO3(aq) + H2O(l)   1/Ka2(H2CO3)=1/4.7x10–11
Sum  CaCO3(s) + H3O+(aq)  ::equil:: Ca2+(aq) + HCO3(aq) + H2O(l)   Ksum

Ksum = Ksp(CaCO2)/Ka(HCO3) = 3.36×10–9 / 4.7×10–11 = 71.5.


I understand the summation of the reactions, but I do not understand Ksum, what it is and why it is division and not addition...
Can anyone please explain this to me?  ???
« Last Edit: February 20, 2010, 02:19:15 PM by Kritkatten »

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