April 19, 2024, 09:49:58 PM
Forum Rules: Read This Before Posting


Topic: Li/NH3 and alkenes  (Read 14120 times)

0 Members and 1 Guest are viewing this topic.

Offline grad05

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
Li/NH3 and alkenes
« on: July 26, 2010, 05:31:22 PM »
Hi,

I was just wondering if anyone might be able to help me with my confusion over the reactivity of Li/NH3.  I understand that this combination of reagents can reduce an alkyne into a trans-alkene,but will these same reagents reduce an alkene to an alkane??  More specifically, will Li/NH3 reduce 1-methyl-3-cyclopentene into a cyclopentane or possibly open up the cyclic compound in some manner??

Offline SVXX

  • Full Member
  • ****
  • Posts: 104
  • Mole Snacks: +4/-0
  • Gender: Male
  • The Bleh
    • My Twitter Page
Re: Li/NH3 and alkenes
« Reply #1 on: July 28, 2010, 10:59:27 AM »
No, it doesn't reduce alkenes. For more info, -: http://www.chem.ucalgary.ca/courses/350/Carey5th/Ch09/ch9-7.html
Organic Mania

Sponsored Links