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Topic: Bond energies, check my problem?  (Read 3827 times)

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Offline THISMOMENTISFATE

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Bond energies, check my problem?
« on: April 26, 2010, 11:52:16 PM »
Bond energies, check my problem?
im trying to solve this problem, can someone check where i made the mistake?

Calculate the Hrxn using Bond energies (BE) for the following reaction.
N2 BE=945 kJ H2 BE=432 kJ N-H BE=391 kJ

N2 + 3H2 ---> 2NH3


Solution:

945 + 3(432) --> 2(391 x 3)
2241---> -2345
= -105

but the problem says the right answer is -2346

i have a test tomorrow,, can someone help?

Offline Wald_ron

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Re: Bond energies, check my problem?
« Reply #1 on: April 27, 2010, 12:11:06 AM »
 :delta:H rxn = H products - H reactants
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Offline THISMOMENTISFATE

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Re: Bond energies, check my problem?
« Reply #2 on: April 27, 2010, 12:23:22 AM »
i tried that i stilll dont get the right answer'

Offline Borek

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Re: Bond energies, check my problem?
« Reply #3 on: April 27, 2010, 03:19:23 AM »
IMHO answer you have listed is incorrect. 2346 = 2*3*391, seems like 2346 is total bond energy in products, not Hrxn.
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Offline THISMOMENTISFATE

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Re: Bond energies, check my problem?
« Reply #4 on: April 27, 2010, 10:19:55 AM »
ive tried to solve it two ways does anyone know which one is right?


[945 + 3 (432) ] - [2(391) + 432]
2241-1214
1027


or:

[945 + 3 (432) ] - [6(391) ]
2241-2346
-105

which one is right, does anyone know?

Offline Astatine

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Re: Bond energies, check my problem?
« Reply #5 on: April 27, 2010, 11:55:45 AM »
I believe that -105kJ/mol is indeed the correct answer.

Offline THISMOMENTISFATE

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Re: Bond energies, check my problem?
« Reply #6 on: April 27, 2010, 12:52:26 PM »
Thanks, for the help everyone!

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