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Topic: Reactivity  (Read 3822 times)

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Offline Saionji

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Reactivity
« on: August 14, 2010, 09:35:50 PM »
I would like to know if the reactivity of these rings are diferent, because i can found nothing that could help this.


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Offline Jorriss

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Re: Reactivity
« Reply #1 on: August 14, 2010, 09:41:36 PM »
So, the two outside rings will have the same reactivity but the middle will be different. Frankly though, I'd suspect it to be a small difference.

Offline discodermolide

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Re: Reactivity
« Reply #2 on: August 14, 2010, 11:48:33 PM »
I would like to know if the reactivity of these rings are diferent, because i can found nothing that could help this.


http://img690.imageshack.us/img690/6895/imagemhj.png

You will not see any reactivity differences in this system
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Offline Saionji

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Re: Reactivity
« Reply #3 on: August 15, 2010, 12:47:24 PM »
Since the middle will be equal ? Sorry, but why?

Offline ardbeg

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Re: Reactivity
« Reply #4 on: August 15, 2010, 08:16:43 PM »
the system is completely conjugated.

Offline Jorriss

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Re: Reactivity
« Reply #5 on: August 15, 2010, 08:21:56 PM »
Hmm, would that make all three rings entirely equal though? I'm now thinking, yes.

Offline Saionji

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Re: Reactivity
« Reply #6 on: September 05, 2010, 01:45:32 PM »
I did not know if you saw, but in the upper ring the ligation pi is on a different position. The reactivity is not equal because of it?

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