April 29, 2024, 01:27:49 PM
Forum Rules: Read This Before Posting


Topic: Isomerism and Acidity  (Read 1900 times)

0 Members and 1 Guest are viewing this topic.

Offline desadevil

  • New Member
  • **
  • Posts: 7
  • Mole Snacks: +0/-0
  • Gender: Female
Isomerism and Acidity
« on: September 25, 2010, 07:27:57 AM »
I was wondering if anyone could tell me how cis-trans isomerism affects acidity?
For example, how does the configuration of maleic (cis-butenedioic) acid render it higher in acidity than its trans counterpart (fumaric acid)? Since the inductive effect explanation doesn't seem to apply here... ???
Thanks in advance!  ;)

Offline Jorriss

  • Chemist
  • Full Member
  • *
  • Posts: 523
  • Mole Snacks: +41/-14
Re: Isomerism and Acidity
« Reply #1 on: September 26, 2010, 12:28:26 AM »
My guess is in the cis configuration you can get some intramolecular forces going on.

Sponsored Links