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Topic: Find the specific rotation.  (Read 16637 times)

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Offline nbmt1227

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Find the specific rotation.
« on: November 03, 2010, 10:04:16 PM »
Question: A 0.100 M solution of an enantiomerically pure chiral compound D has an observed rotation of +0.24 in a 1-dm sample container. The molar mass of the compount is 142.0 g/mol.

(a) What is the specific rotation of D?

Attempting to work out the problem: So I understand that I'm using the formula [specific rotation = observed rotation / (c*l)]. So here is how I tried to find c:

.100 M = mol/L
142 g/mol

.1*142 =14.2 g/L* 1 L/ 1000 mL = .0142

So the equation would me +0.24/(.0142)(1)...
...making the specific rotation 16.9014

(b) what is the observed rotation if this solution is mixed with an equal volume of a solution that is 0.100 M in L, the enantiomer of D?

Attempt: Does this mean I add an additional .100 M to my equation?
Sort of like:

16.9014 = observed rotation/ 2(.0142)

I don't quite understand the question and would appreciate if you could help me out.
I thank you in advance.

Offline Cherriyan

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Re: Find the specific rotation.
« Reply #1 on: November 04, 2010, 07:58:53 AM »
Try to think what happens when equal amounts of two enantiomers of same compound are mixed. What is the optical rotation of a racemic mixture?

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