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### Topic: reacting masses and gaseous and solution volumes  (Read 3770 times)

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#### PhilipCheney

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##### reacting masses and gaseous and solution volumes
« on: November 15, 2010, 12:20:14 AM »

I am having trouble with a question below:

Magnesium reacts with dilute hydrochloric acid:
I wrote the equation as:
Mg(S)+ 2H+ (aq):Mg(aq)+H2(g)
If 0.720 g of magnesium is treated with 0.950 mol L -1of hydrochloric acid calculate the:
(a) The volume of hydrocholric acid needed to react with all the magnesium

What I did for a was use the mole statment and the formula n=m
M
and the n= V
22.4

However I got the answer incorrect because I think I used the wrong forumals.
What are the steps to calculate the volume of HCL

Thank you

#### Fluorine

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##### Re: reacting masses and gaseous and solution volumes
« Reply #1 on: November 15, 2010, 12:37:42 AM »
Magnesium reacts with dilute hydrochloric acid:
I wrote the equation as:
Mg(S)+ 2H+ (aq):Mg(aq)+H2(g)

Where the chlorine? Shouldn't the reaction of HCl with Mg be;

Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)
I'm still learning - always check my work/answer.

"curse Pierre Jules César Janssen!"

#### sjb

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##### Re: reacting masses and gaseous and solution volumes
« Reply #2 on: November 15, 2010, 03:58:49 AM »
I am having trouble with a question below:

Magnesium reacts with dilute hydrochloric acid:
I wrote the equation as:
Mg(S)+ 2H+ (aq):Mg(aq)+H2(g)
If 0.720 g of magnesium is treated with 0.950 mol L -1of hydrochloric acid calculate the:
(a) The volume of hydrocholric acid needed to react with all the magnesium

What I did for a was use the mole statment and the formula n=m
M
and the n= V
22.4

However I got the answer incorrect because I think I used the wrong forumals.
What are the steps to calculate the volume of HCL

Thank you

No, this formula would only be for ideal gases at stp (I think, from the limited information you have given), which an aqueous solution of hydrochloric acid is not. What equations do you know that relate solution concentration to amount of substance?

You have (correctly) identified the balanced equation for the reaction. Now, how many moles of magnesium do you have? How much HCl?

Where the chlorine? Shouldn't the reaction of HCl with Mg be;

Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

Pedantically, it's chloride, but in any event it is unchanged during the reaction - have you heard of spectator ions?

#### Borek

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##### Re: reacting masses and gaseous and solution volumes
« Reply #3 on: November 15, 2010, 04:47:06 AM »
Mg(S)+ 2H+ (aq):Mg(aq)+H2(g)

Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

"Net ionic" is the keyword here.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info, pH-meter.info

#### Fluorine

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##### Re: reacting masses and gaseous and solution volumes
« Reply #4 on: November 15, 2010, 06:08:48 AM »
@SJB + Borek

I'm aware of spectator ions and net ionic format. When I read "equation" and "volume of HCl" I assumed the full equation was necessary. SJB I'm not sure why I said chlorine, I know better. Apologies on both fronts.
I'm still learning - always check my work/answer.

"curse Pierre Jules César Janssen!"