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Topic: Most acidic solution?  (Read 5530 times)

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Offline LHM

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Most acidic solution?
« on: December 05, 2010, 09:01:10 PM »
Which of these ions is predicted to produce the most acidic solution when dissolved in H2O?

A) K+
B) Ba2+
C) Co2+
D) Fe 3+

The answer is D, but why would Fe3+(aq) produce a more acidic solution than Co2+(aq)?

Offline Fluorine

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Re: Most acidic solution?
« Reply #1 on: December 05, 2010, 10:42:27 PM »
An acidic solution contains a lot of H+ and minimal of OH-, right? Let's think what happens when you have these cations in water. The equation, essentially, would follow;

H2O + Mn  ::equil:: M(OH)n + H+
or
H+ + OH- + Mn  ::equil:: M(OH)n + H+

where M is representative for the listed cations and n is their charge number, respectively. Co+2 would form Co(OH)2 and Fe+3 would form Fe(OH)3, the cobalt leaving 2H+ and the iron leaving 3H+.
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