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Is this a trick question? About bond dissociation energy
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Topic: Is this a trick question? About bond dissociation energy (Read 3254 times)
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chronicconic
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Is this a trick question? About bond dissociation energy
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on:
December 15, 2010, 02:11:50 PM »
In the lab, it was determined that the bond dissociation energy for a C-H bond is 213kJ/mol?
How much energy would be required to break a single C-H bond?
I decided it was either 213kJ/6.022x10^23 = 3.54 x10^-22kJ, or 213kJ. I'm not sure
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opti384
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Re: Is this a trick question? About bond dissociation energy
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Reply #1 on:
December 15, 2010, 08:29:28 PM »
I'm pretty sure it's the latter.
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chronicconic
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Re: Is this a trick question? About bond dissociation energy
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December 16, 2010, 12:13:51 AM »
I can't see how it could be the prior. I mean, 3.54x10^-32kJ seems like a ridiculously small amount of energy to break a C-H bond.
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saden99
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Re: Is this a trick question? About bond dissociation energy
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Reply #3 on:
December 16, 2010, 02:09:37 AM »
Latter means the second of those mentioned. So he was saying 213kJ seems like the reasonable answer.
And with just that information I would say the same thing. Your calculation doesn't quite make sense...Avogadro's constant has units that you have to take into account (in this case 1/mol). This wouldn't be canceled out anywhere and...I think you'd be left with kJ-mol^-1...which again gets your no where.
This would be a question where intuition plays a role. Yes.....3.54 x10^-22kJ is way to small an amount of energy to break a C-H bond.
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tamim83
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Re: Is this a trick question? About bond dissociation energy
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Reply #4 on:
December 16, 2010, 05:02:04 PM »
Actually the first answer is
very
reasonable if you consider the size of a molecule. Energies should be on the order of 10
-19
J (a few electron-volts). Trust me, I'm a physical chemist; go with your first answer.
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Last Edit: December 16, 2010, 06:17:50 PM by Borek
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ifross
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Re: Is this a trick question? About bond dissociation energy
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Reply #5 on:
December 23, 2010, 09:32:12 PM »
The correct answer is 3.54x10^-19J (your first answer). 213KJ is the energy needed to break 1 mol of bonds, i.e. 6x10^23 CH bonds, so to find out how much energy is needed to break one bond, you divide by this as you did.
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Is this a trick question? About bond dissociation energy