April 26, 2024, 06:14:41 PM
Forum Rules: Read This Before Posting


Topic: Chemical reaction H[CuCl2]  (Read 21518 times)

0 Members and 1 Guest are viewing this topic.

Offline Baltic Beazt

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
Chemical reaction H[CuCl2]
« on: February 02, 2011, 01:17:39 PM »
hi.
I was given a task to come up with chemical reaction in which from
CuCl2 I was suposed to get H[CuCl2]
now in answers this reaction is shown

CuCl2 + Cu + HCl  :rarrow: 2H[CuCl2]

Can anyone explain why is this happening and what exactly H[CuCl2] is.

Offline DevaDevil

  • Chemist
  • Full Member
  • *
  • Posts: 690
  • Mole Snacks: +55/-9
  • Gender: Male
  • postdoc at ANL
Re: Chemical reaction H[CuCl2]
« Reply #1 on: February 04, 2011, 11:51:25 AM »
copper (I) chloride complex: CuCl2- is a complex of CuCl and HCl
CuCl does not dissolve much in water, but complexing with the concentrated hydrochloric acid gives this complex and dissolution.

What happens in your reaction is that you have copper (II) chloride, CuCl2 (s), which can complex with additional halide atoms (e.g. chlorides), to form [CuCl2+x]-x.
then the addition of copper metal sets off a redox reaction, in which the copper (0) is oxidized and the copper (II) reduced to form the cooper (I) complex (in hydrochloric acid)

half-reactions:

CuCl2 + HCl + e- --> H[CuCl2] + Cl-
Cu (s) + HCl + Cl- --> H[CuCl2] + e-

Sponsored Links