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Topic: Calculating Kc for different reactions  (Read 6436 times)

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Offline HorseFurHire

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Calculating Kc for different reactions
« on: February 13, 2011, 07:41:13 PM »
Hey all, I'm really stumped. I'm taking the second half of a first year chem course and since I took a break from between classes, which resulted in me forgetting what I knew before. The problem is this:

Determine Kc for the reaction:

1/2N2(g) + O2(g) + 1/2 (g) (equilibrium sign) NOBR (g)

from the following information (at 298 K):

2 NO (g) (equilibrium sign) N2 (g) + O2 (g)
Kc = 2.1 x 1030

NO (g) + 1/2 Br2 (g) (equilibrium sign) NOBr (g)
Kc = 1.4

(Those Kc values at the end are paired with the reactions)

My problem comes into play with not knowing what formula to use to calculate this... Help?

Offline opti384

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Re: Calculating Kc for different reactions
« Reply #1 on: February 13, 2011, 08:04:25 PM »
Try to get the first equation by adding and subtracting the ones that you know the Kc.


Offline HorseFurHire

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Re: Calculating Kc for different reactions
« Reply #2 on: February 13, 2011, 08:23:40 PM »
Try to get the first equation by adding and subtracting the ones that you know the Kc.

So minus the second one from the first one?

Offline opti384

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Re: Calculating Kc for different reactions
« Reply #3 on: February 13, 2011, 08:32:03 PM »
Actually it doesn't matter to subtracting which from which because you can reverse the equation if necessary.

Just try to make this equation
Quote
1/2N2(g) + O2(g) + 1/2 (g) (equilibrium sign) NOBR (g)


The thing is that do you know what happens to the Kc when you add and subtract equations?


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