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Naming an alcohol systematically?
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Topic: Naming an alcohol systematically? (Read 4534 times)
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DannyBoi
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Naming an alcohol systematically?
«
on:
February 21, 2011, 04:57:58 PM »
Hi,
Can anyone explain how to fix this answer?
I figure you count the longest chain with the hydroxy group on it, then name the second carbon substituent which I would think is sec-butyl?
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Doc Oc
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Re: Naming an alcohol systematically?
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Reply #1 on:
February 21, 2011, 07:14:16 PM »
Your thinking is correct, but you need to be more explicit when using IUPAC nomenclature. You can't use sec-butyl, try something else.
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cswarth
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Re: Naming an alcohol systematically?
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Reply #2 on:
February 22, 2011, 03:15:28 AM »
There are two 5-carbon chains ending in with a hydroxy group.
Would it be just as valid to go down the other chain and name it 2-propyl-3-methyl pentanol?
Or does IUPAC want you to minimize the number of substituents?
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DannyBoi
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Re: Naming an alcohol systematically?
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Reply #3 on:
February 22, 2011, 12:52:12 PM »
Oh I didn't see the other chain! But I think your name is correct. Because it is simpler to go down the chain that has the simplest branching on it?
If not then, I would guess that I would have to name it 2-(1-methylpropyl)-1-pentanol?
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Doc Oc
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Re: Naming an alcohol systematically?
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Reply #4 on:
February 22, 2011, 03:23:14 PM »
I think cswarth's answer is more along the correct lines.
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DannyBoi
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Re: Naming an alcohol systematically?
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Reply #5 on:
February 22, 2011, 04:30:45 PM »
Yes I believe it is best to use the simplest branching chain when given the choice! Thanks
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Naming an alcohol systematically?