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Topic: Chemistry of iodosobenzene diacetate  (Read 3588 times)

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Offline AB01

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Chemistry of iodosobenzene diacetate
« on: February 27, 2011, 03:11:51 PM »
Hi everyone,

I am looking for use and chemistry of iodosobenzene diacetate so please can anyone explain me specially regarding its reaction with Pd(II) species and possible mechanism.

Thanks
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Offline MissPhosgene

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Re: Chemistry of iodosobenzene diacetate
« Reply #1 on: February 27, 2011, 03:41:09 PM »
Here:

J. AM. CHEM. SOC. 2007, 129, 5836-5837
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Stereograms of the 32 crystallographic point groups: little bike wheels of cold, hard, pure rationality.

Offline 408

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Re: Chemistry of iodosobenzene diacetate
« Reply #2 on: February 28, 2011, 01:49:25 AM »
It turns a aromatic nitro next to an amino into a furoxan...
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Offline kreisler

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Re: Chemistry of iodosobenzene diacetate
« Reply #3 on: March 01, 2011, 09:11:53 AM »
iodosobenzene diacetate is a good oxidant which can promote the oxidation of Pd(II) to Pd(IV). It's was used widely in C-H activation reactions.
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