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Topic: Mass of Nuclide Remaining After a Fraction of a Half-Life  (Read 4818 times)

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Offline sugarwink

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Mass of Nuclide Remaining After a Fraction of a Half-Life
« on: April 09, 2011, 11:26:14 PM »
You want to do an experiment using 47Ca (half-life=4.53 days). You will need 3.80 μg of the nuclide. What mass of CaCO3 (100% enriched in 47Ca) must you order if it will take 33 hours to be delivered to you from the nuclear facility where it is prepared?

time of transport / half life = n
33 hrs / 108.72 hrs = n
n = 0.303432009

1/2^n = x
x = 0.810266271

This is how far I've gotten, where am I suppose to go from here?

Offline Schrödinger

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Re: Mass of Nuclide Remaining After a Fraction of a Half-Life
« Reply #1 on: April 10, 2011, 12:53:42 AM »
Using the half-life data, find out the rate constant for the decay of 47Ca.
Then, use the first order integrated rate equation, with the unknown being the initial mass (or equivalently, moles).

For the rate equation :
k,t (33 hrs) and final mass (3.80 μg) are known. All you have to do is find the initial mass.
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Offline sugarwink

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Re: Mass of Nuclide Remaining After a Fraction of a Half-Life
« Reply #2 on: April 10, 2011, 01:13:18 AM »
t1/2 = ln(2) / k
108.72hrs = ln (2) / k
k = 0.006375526

ln(N/Ninitial) = - kt
ln(3.80μg/Ninitial) = - (0.006375526)(33hrs)
Ninitial = 4.69μg

Where am I going wrong? I am still confused.

Offline Borek

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Re: Mass of Nuclide Remaining After a Fraction of a Half-Life
« Reply #3 on: April 10, 2011, 04:27:41 AM »
4.69 μg looks OK to me, but so far it is a mass of nuclide - that's not what you order.
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