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Topic: urgent help:generation of HS- from P2S5 balancing reaction  (Read 3243 times)

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Offline cauton1497

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urgent help:generation of HS- from P2S5 balancing reaction
« on: April 17, 2011, 04:29:11 PM »
I need to balance this equation:

P2S5 + C18H35(NH2) --> HS- + compound 1 + compound 2

I am told:
compound 1: contains phosphorus and possibly leftover sulfur and "reacts" with amine
compound 2: does not contain phosphorus or sulfur and has to balance out the charge on the hydrosulfide ion

My best guess is P2S5 + C18H35(NH2) --> 5HS- + 2P + C18H33(NH3)+ but clearly there is a problem with the hydrogens and I don't think this is correct.

Please help

Offline ithinkiknow

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Re: urgent help:generation of HS- from P2S5 balancing reaction
« Reply #1 on: April 23, 2011, 10:58:58 PM »
it might help that P2S5 is a dimer in the form P4S10 which has a stable P4S8 derivative. assuming 2 amines each generating 1 H+ that would lead to 2HS- and P4S8 (most likely alpha form).

Hope that helps.

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