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Topic: Structure of IF6-?  (Read 13746 times)

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Offline Fzang

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Structure of IF6-?
« on: June 05, 2011, 04:14:59 PM »
I have this weird problem that goes:

"Structural analysis has proven that IF6- is not octahedral. Account for this result"

I'm kind of lost. If it's not octahedral, what then?

EDIT: Okay, so it has a lonepair, on top of the octahedral configuration with fluoride. So it's gotta be some distorted version of the octahedral, because the lone pair is budging around here and there?

Offline Schrödinger

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Re: Structure of IF6-?
« Reply #1 on: June 06, 2011, 04:25:43 AM »
http://en.wikipedia.org/wiki/Xenon_hexafluoride
Read under "Structure"

In the IF6- ion, the negative charge is borne by the Iodine atom. Since the electronic configuration of I- is the same as that of Xe, I think their structures will similar.
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Offline BluePill

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Re: Structure of IF6-?
« Reply #2 on: June 07, 2011, 10:28:07 AM »
hint: it's a C5v molecule.  ;D

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