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Topic: All aldoses exhibit mutarotation? please help me with this question.  (Read 2908 times)

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Offline chunli

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Hello helpful people,

I don't understand this question, please help me.
Thanks in advance=)


All aldoses exhibit mutarotation. For example, α-D-galactopyranose has
[α]D = +150.7 and β-D-galactopyranise has [α]D = +52.8. If either anomer
is dissolved in water and allowed to reach equilibrium, the specific
rotation of the solution is +80.2. What are the percentages of each
anomer at equilibrium? Draw the pyranose forms of both anomers.

Offline sjb

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Re: All aldoses exhibit mutarotation? please help me with this question.
« Reply #1 on: December 18, 2011, 09:19:12 AM »
Hello helpful people,

I don't understand this question, please help me.
Thanks in advance=)


All aldoses exhibit mutarotation. For example, α-D-galactopyranose has
[α]D = +150.7 and β-D-galactopyranise has [α]D = +52.8. If either anomer
is dissolved in water and allowed to reach equilibrium, the specific
rotation of the solution is +80.2. What are the percentages of each
anomer at equilibrium? Draw the pyranose forms of both anomers.

What are you having difficulty with? Without a start, I am not sure how to lead.

Offline Dan

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Re: All aldoses exhibit mutarotation? please help me with this question.
« Reply #2 on: December 18, 2011, 07:14:26 PM »
Start here: http://en.wikipedia.org/wiki/Mutarotation

That page actually provides all the information you need. Study it and we can clarify anything you are specifically unsure about.
« Last Edit: December 18, 2011, 07:34:15 PM by Dan »
My research: Google Scholar and Researchgate

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