April 25, 2024, 07:39:37 PM
Forum Rules: Read This Before Posting


Topic: C4 hydrocarbons calibration -- FID signal  (Read 2200 times)

0 Members and 1 Guest are viewing this topic.

Offline crt

  • Regular Member
  • ***
  • Posts: 21
  • Mole Snacks: +1/-1
C4 hydrocarbons calibration -- FID signal
« on: February 29, 2012, 05:53:47 AM »
Hello,

I want to calibrate C4 hydrocarbons on a GC and would like to ask if one has experience with this. Is the detectorsignal identical for the isomers (1-butene + 2-butenes + i-butene and n-butane + i-butane)? I would like to know if we have to order all isomers or for example 1-butene and n-butane are enough if the retention times are known. I have FID.

Thanks
crt

Offline Stepan

  • Chemist
  • Full Member
  • *
  • Posts: 358
  • Mole Snacks: +39/-4
  • Gender: Male
  • Air Chemistry Man
    • Supplier of air sampling equipment and services
Re: C4 hydrocarbons calibration -- FID signal
« Reply #1 on: February 29, 2012, 06:57:58 AM »
The response factor will be all the same. Variation is +/- 5% or less. The biggest difference will be between butane and butene. 

Offline crt

  • Regular Member
  • ***
  • Posts: 21
  • Mole Snacks: +1/-1
Re: C4 hydrocarbons calibration -- FID signal
« Reply #2 on: February 29, 2012, 07:08:43 AM »
Hey Stepan,

thanks a lot. I want to calibrate one olefin and one alkane but then I need one of each.

crt

Sponsored Links