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Topic: Ionization Energy and Calculating Heat Released...  (Read 3427 times)

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Offline BriaM

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Ionization Energy and Calculating Heat Released...
« on: March 16, 2012, 06:05:33 AM »
Someone please help me!  :-[

Given the following data, estimate the energy released when gaseous K and I atoms form gaseous [K+I-]. neglect anything about lattice information

Element EA (kJ/mol)      IE1 (kJ/mol)        IE2 (kJ/mol)         Ion Radius( pm)
K                -48.4            418.8             3051       133(cation)
I                 -295.3           1008.4           1845.9      220 (anion)

The answer is -270kj/mol
please anyone help me on how to get this question because am stuck.. also frustrated..ugg! ;( I'm not even sure of how to approach it.

Offline fledarmus

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Re: Ionization Energy and Calculating Heat Released...
« Reply #1 on: March 16, 2012, 07:24:29 AM »
In your own words, what information are you given in the table you posted?

Offline BriaM

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Re: Ionization Energy and Calculating Heat Released...
« Reply #2 on: March 16, 2012, 08:54:02 AM »
I am given the electron affinities for potassium and iodine which are -48.4 and -295.3. Then I have the first and second ionization energies for both elements. Potassium at 418.8 and 3051 respectively and iodine with 1008.4 and 1845.9. The electron affinity and ie have units of kj/mol. Finally we are given the ion radius with potassium at 133 pm and iodine at 220 pm. We have to neglect lattice formation. I tried incorporating Coloumbs law but we aren't allowed to use it...

Offline fledarmus

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Re: Ionization Energy and Calculating Heat Released...
« Reply #3 on: March 16, 2012, 09:44:09 AM »
What reaction does the energy of ionization represent?

Offline BriaM

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Re: Ionization Energy and Calculating Heat Released...
« Reply #4 on: March 16, 2012, 10:03:40 AM »
The minimum energy need to remove the highest energy electron from the neutral ago
   In the gaseous state

Offline BriaM

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Re: Ionization Energy and Calculating Heat Released...
« Reply #5 on: March 16, 2012, 11:22:53 AM »
Anyone?

Offline fledarmus

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Re: Ionization Energy and Calculating Heat Released...
« Reply #6 on: March 16, 2012, 01:32:38 PM »
Okay, so how would you write that reaction?

And likewise, what reaction does the electron affinity represent? And how would you write that reaction?

Offline BriaM

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Re: Ionization Energy and Calculating Heat Released...
« Reply #7 on: March 16, 2012, 04:00:54 PM »
Yeah, nevermind. I used the equation E = kQ1Q2/r. plugged in values and got -270.

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