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### Topic: how to measure the standard electrode of cl2 with reference to standard hydrogen  (Read 1567 times)

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#### will_L

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##### how to measure the standard electrode of cl2 with reference to standard hydrogen
« on: May 10, 2012, 10:31:48 AM »
how to draw the cell diagram of cl2.

Given e.m.f of the cell at standard conditions is +1.36v

reactions at the electrodes are: H(g) = (H+)(aq) + e

and  Cl2(g) + (2e-) = (2Cl-)(aq)

giving an overall cell reaction :  Cl2(g) + H2(g) = (2Cl-)(aq) + (2H+)(aq)

#### ramboacid

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##### Re: how to measure the standard electrode of cl2 with reference to standard hydrogen
« Reply #1 on: May 10, 2012, 12:28:49 PM »
I would guess that you would use platinum electrodes in both of the cells.
Pt|H2, H+||Cl2, Cl-|Pt

http://en.wikipedia.org/wiki/Standard_hydrogen_electrode
"Opportunity is missed by most people because it is dressed in overalls and looks like work." - Thomas Edison

#### will_L

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##### Re: how to measure the standard electrode of cl2 with reference to standard hydrogen
« Reply #2 on: May 10, 2012, 06:53:10 PM »
yeah, but why is it Cl2(g) beside the salt bridge(//) instead of Cl- ? i thot the ions suppose to be next to the salt bridge.

#### ramboacid

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##### Re: how to measure the standard electrode of cl2 with reference to standard hydrogen
« Reply #3 on: May 10, 2012, 07:42:38 PM »
Quote
yeah, but why is it Cl2(g) beside the salt bridge(//) instead of Cl- ? i thot the ions suppose to be next to the salt bridge.
I wrote the ions by the platinum electrode because that is where reduction occurs, at the cathode. The Cl2 is reduced to Cl- ions at the cathode and H2 is oxidized to H+ at the anode.

I'm not very familiar with line notation for galvanic cells, so my notation might be wrong. I wrote it so that you could "read" the reaction from left to right (H2 is oxidized to H+ and Cl2 is reduced to Cl-).
"Opportunity is missed by most people because it is dressed in overalls and looks like work." - Thomas Edison

#### will_L

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##### Re: how to measure the standard electrode of cl2 with reference to standard hydrogen
« Reply #4 on: May 10, 2012, 08:02:23 PM »
it is correct, cl2(g) and cl- shud be seen as a whole. thanks a lot.