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Topic: Can ammonium ionize in water?  (Read 6471 times)

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Offline whylolzz

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Can ammonium ionize in water?
« on: May 17, 2012, 08:46:05 AM »
Hey guys,
I know acids such as HCl can ionize in water: HCl + H2O :rarrow: H3O+ + Cl-
But can an ion such as ammonium ionize? NH4+ + H2O ::equil:: NH3 + H3O+

Also, is ammonium a weak acid? (since it's a conjugate of a base NH3)

Thanks for your help :)

Offline AWK

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Re: Can ammonium ionize in water?
« Reply #1 on: May 17, 2012, 09:00:35 AM »
Why pH of, say, NH4Cl in water is about 5?
AWK

Offline whylolzz

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Re: Can ammonium ionize in water?
« Reply #2 on: May 17, 2012, 09:07:05 AM »
Why pH of, say, NH4Cl in water is about 5?
Are you referring to the part where I mentioned whether ammonium is a weak acid?
If so, you can tell straight away that the chloride ions can't hydrolize in water while ammonium can (and forms hydronium ions - indicating it's an acid)
Anyway, so can you confirm whether ammonium itself is capable of ionizing in water? For instance, can you have concentrated/dilute solutions of ammonium in water?

Thanks for your time

Offline cheese (MSW)

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Re: Can ammonium ionize in water?
« Reply #3 on: May 17, 2012, 08:21:50 PM »
We don't give answers directly on this forum.
Review your notes on conjugate acids/bases and,
Calculate the pH of 0.10 M [NH4]Cl
Hint: pKa + pKb =  pKw = ~14
Given pKb(NH3) = 4.75
http://en.wikipedia.org/wiki/Ammonia
Compare answer to AWK's post.   ;) 

Offline whylolzz

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Re: Can ammonium ionize in water?
« Reply #4 on: May 18, 2012, 04:37:08 AM »
We don't give answers directly on this forum.
Review your notes on conjugate acids/bases and,
Calculate the pH of 0.10 M [NH4]Cl
Hint: pKa + pKb =  pKw = ~14
Given pKb(NH3) = 4.75
http://en.wikipedia.org/wiki/Ammonia
Compare answer to AWK's post.   ;) 

This isn't my homework or anything.. It was from my exam and I was wondering whether I had got it right. I was just curious whether ammonium can ionize in water if it's already an ion, and if it can, can you have diluted/concentrated solutions of it.

Offline AWK

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AWK

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