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Topic: Vinyl Chloride  (Read 5741 times)

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Offline Nitin_Naudiyal

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Vinyl Chloride
« on: June 10, 2012, 11:15:24 AM »
There's a Multiple Choice question in my Text book

In its Nucleophilic substitution reaction , aryl halide resembles

a) Vinyl Chloride
b) allyl chloride
c) Benzyl Chloride
d) ethyl chloride

The answer given is a) Vinyl chloride

I want to ask is Since aryl halide is an aromatic compound how can the Answer be Vinyl Chloride ?

Offline discodermolide

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Re: Vinyl Chloride
« Reply #1 on: June 10, 2012, 12:17:31 PM »
There's a Multiple Choice question in my Text book

In its Nucleophilic substitution reaction , aryl halide resembles

a) Vinyl Chloride
b) allyl chloride
c) Benzyl Chloride
d) ethyl chloride

The answer given is a) Vinyl chloride

I want to ask is Since aryl halide is an aromatic compound how can the Answer be Vinyl Chloride ?

They are asking for the ease of nucleophilic substitution, nucleophilic substitution in aryl halides and vinyl halides requires special conditions and does not occur under "normal" conditions.
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Offline Nitin_Naudiyal

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Re: Vinyl Chloride
« Reply #2 on: June 12, 2012, 12:07:46 AM »
Sry But i didnot understand .
Can you please Explain it to me once again

Offline discodermolide

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Re: Vinyl Chloride
« Reply #3 on: June 12, 2012, 01:38:30 AM »
Sry But i didnot understand .
Can you please Explain it to me once again

What do you not understand?
You know what nucleophilic substitution is I assume?
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Offline Nitin_Naudiyal

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Re: Vinyl Chloride
« Reply #4 on: June 13, 2012, 01:29:59 AM »
I know that nucleophilic substitution reaction means that a nucleophile
attacking an electrophile

but i didnot understand the question
Quote
In its Nucleophilic substitution reaction , aryl halide resembles

What do they exactly want to ask ?
resembles in the sense what ?
Reaction mechanism
Structure
Compound
Functional group

Offline discodermolide

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Re: Vinyl Chloride
« Reply #5 on: June 13, 2012, 01:43:54 AM »
I know that nucleophilic substitution reaction means that a nucleophile
attacking an electrophile

but i didnot understand the question
Quote
In its Nucleophilic substitution reaction , aryl halide resembles

What do they exactly want to ask ?
resembles in the sense what ?
Reaction mechanism
Structure
Compound
Functional group

They are talking about structure. In vinyl and aryl halides you have an electron rich pi electron cloud which can be seen a clouds of negative charge about the C-C bonds. A nucleophile cannot approach this as a nucleophile has a negative charge, like repels like. So in vinyl and aryl halides the nuleophilic reaction cannot occur unless very special conditions are used.

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Offline Nitin_Naudiyal

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Re: Vinyl Chloride
« Reply #6 on: June 13, 2012, 02:30:43 AM »
Thanks you discodermolide for your help

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