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Offline liukawa

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Question on Acid , Bases & Salt
« on: June 18, 2012, 10:32:39 AM »
Hi Guys,

I have a high school question which I need help urgently . Appreciate if anyone can help !

The question is as follows :

Quote
"The metal nickel (Ni) has a valency of 2. When excess sodium hydroxide solution was added to a solution of nickel chloride, nickel hydroxide was precipitated. This precipitate was filtered, washed and heated , leaving a residue of 0.747g of pure nickel oxide. This residue, when heated in a steam of hydrogen, gave 0.590g of metallic nickel.

(a) Write equations with state symbols for the three chemical referred to above.


I manage to come up with these 3 equations.

1. NiCL2 +2NaOH  :rarrow: 2NaCL + Ni(OH)2

2. Ni(OH)2 + O2  :rarrow: NiO + H2O

3. NiO + H2  :rarrow: Ni +H2O

Are my equations correct?

I can't seem to balance the 2nd equation so i suspect my 2nd equation is wrong...

But I have no idea what equation should be formed....

I will also need to calculate the mass of nickel chloride present in the original solution .

Greatly appreciate if any kind souls can help.

Thanks !

Edit: tags corrected
« Last Edit: June 18, 2012, 11:18:24 AM by Borek »

Offline Borek

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Re: Question on Acid , Bases & Salt
« Reply #1 on: June 18, 2012, 11:20:00 AM »
Nickel hydroxide doesn't react with oxygen, just decomposes.

How many moles of Ni in each step?
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Offline liukawa

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Re: Question on Acid , Bases & Salt
« Reply #2 on: June 20, 2012, 11:17:30 AM »
Decompose meaning?

Nickel Hydroxide will decompose to become Nickel and Hydrogen?

Is that right?

Offline Borek

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Re: Question on Acid , Bases & Salt
« Reply #3 on: June 20, 2012, 11:44:10 AM »
Nickel Hydroxide will decompose to become Nickel and Hydrogen?

That would mean oxygen miraculously disappeared.

Your original equation was almost right. Just ignore the oxygen.
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Offline PeonyHamster

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Re: Question on Acid , Bases & Salt
« Reply #4 on: June 22, 2012, 05:18:03 AM »
I think the second equation is
Ni(OH)2 -> NiO + H2O

Offline Borek

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Re: Question on Acid , Bases & Salt
« Reply #5 on: June 22, 2012, 05:20:26 AM »
I think the second equation is
Ni(OH)2 -> NiO + H2O


You think right, but it is not you who should answer this question.
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