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Topic: Mass Spec of Product -Fragmentation  (Read 4263 times)

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Offline Exproxsul

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Mass Spec of Product -Fragmentation
« on: July 30, 2012, 01:26:45 AM »
Hello Gents,

I've got a small problem. I am supposed to analyze my unkown product, which I've found out to be fluorobenzene through HNMR and I.R analysis.
I am unable to analyse the mass spec of the product. I know that the base peak at 96 g  is the M+ peak however im unable to understand what fragments
make up the other peaks. The mass spec im using is the Lit Spec of fluorobenzene that is on sdbs-
http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_frame_disp.cgi?spectrum_type=ms&sdbsno=2445

thanks

Offline discodermolide

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Re: Mass Spec of Product -Fragmentation
« Reply #1 on: July 30, 2012, 06:56:54 AM »
Hello Gents,

I've got a small problem. I am supposed to analyze my unkown product, which I've found out to be fluorobenzene through HNMR and I.R analysis.
I am unable to analyse the mass spec of the product. I know that the base peak at 96 g  is the M+ peak however im unable to understand what fragments
make up the other peaks. The mass spec im using is the Lit Spec of fluorobenzene that is on sdbs-
http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_frame_disp.cgi?spectrum_type=ms&sdbsno=2445

thanks

Looks like the peak at m/z 70 is probably loss of C2H2, (acetylene), the peak at m/z 50 is loss of HF from the peak at m/z 70.
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