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Topic: what happens to the ions in acidic solutions when current flows  (Read 1654 times)

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Offline ajax0604

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I understand why acidic solutions conduct electricity but I am unsure as to what happens when the ions migrate to the electrodes. For example, if there was a solution of NaCl, the Na+ ions will deposit as sodium metal and Cl- ions will form chlorine gas. How about if there was a solution of sulfuric acid? What would happen to the hydronium and sulfate ions when they reach the electrodes?

Offline Hunter2

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Re: what happens to the ions in acidic solutions when current flows
« Reply #1 on: August 21, 2012, 12:44:59 AM »
Hydronium will form Hydrogen

2 H+ + 2 e- => H2

Depending of the concentration Sulfate will replace Oxygen

2 H2O + 2 SO42- => 2 H2SO4 + O2 + 4 e-

or higher concentration it gets  peroxodisulfate

2 SO42- => S2O82- + 2 e-

This happens on inert anodes.

If a metal like copper is used the anode will be dissolved.

Cu + SO42- => CuSO4 + 2 e-

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