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Topic: VSEPR Theory Problem  (Read 2809 times)

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Offline rd55555

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VSEPR Theory Problem
« on: October 05, 2012, 04:50:53 PM »
I am having trouble using VSEPR theory to prove the shape of [Te(tu4)]Cl2. (tu=thiourea) is square planar. The Cl's are not involved with the shape so I'm guessing we are looking at: [Te(tu4)]2+. From this, tellurium has 6 valence electrons and tu has 8 (not sure about this, I think tu donates 2 electrons) and an overall charge of 2+. From this information, I'm not sure how square planar is worked out. Have I made a mistake somewhere?

Thanks in advance.

Offline Hunter2

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Re: VSEPR Theory Problem
« Reply #1 on: October 06, 2012, 10:17:42 AM »
The tellurium-II-ion has only 4 valence electrons. [Kr] 4d10 5s2 5p2, the same like tin Sn. The question now is how the Thiourea is bonded. Does it bonds with the sulfur or the nitrogen. Is it planar or is it a tetraeder?

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