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Topic: Difference between Mesomerism and Resonance  (Read 4823 times)

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Offline Paul2lyfe

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Difference between Mesomerism and Resonance
« on: October 07, 2012, 10:29:59 AM »
I have been wondering and searching.I checked Morrison and Boyd for the difference between Mesomerism and Resonance,but I only get the difference between Mesomerism and Resonance Hybrid.I know Mesomerism involves the movement of pie eectrons in an unsaturated ring trying to make it aromatic or stable and a Resonance hybrid gived characteristics of two resonating structures.But my question still remains what is the difference between Mesomerism and Resonance??

Offline yesway

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Re: Difference between Mesomerism and Resonance
« Reply #1 on: October 07, 2012, 01:00:26 PM »
I think of them as synonymous with the term "Resonance" as being slightly outdated/historical due to the word hinting at a process which is not taking place. In my opinion, there are only mesomeric limit formulae, and a mesomeric hybrid indicated by the double headed arrow. The movement of pi-electrons in this case is only a formality (although an important formality in order to write down mechanisms).

Offline curiouscat

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Re: Difference between Mesomerism and Resonance
« Reply #2 on: October 08, 2012, 01:24:12 PM »
Reminded me of the M&B analogy for resonance I loved:

Quote
It's like trying to describe a rhinoceros as a cross between a dragon and a unicorn.

Offline PhDoc

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Re: Difference between Mesomerism and Resonance
« Reply #3 on: October 10, 2012, 12:37:25 AM »
M&B really does need to catch up to the 21st century. I haven't heard that term used since 1983!

Resonance, there's no substitute.
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