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Topic: soluble Berlin Blue  (Read 1808 times)

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Offline chehemi123

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soluble Berlin Blue
« on: November 27, 2012, 05:12:58 PM »
hi guys..

i´m looking for an orbital energy diagram of soluble Berlin Blue:

K[FeIIIFeII(CN)6]

can you help me?

Offline chehemi123

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Re: soluble Berlin Blue
« Reply #1 on: December 02, 2012, 07:54:46 AM »
hey... i found an orbital energy diagram of CN- and Fe[(H2O)6]2+.

I need the energy diagram of KFe(III)[Fe(II)(CN)6] (soluble berlin blue).
I am not sure how i can combine the diagram of CN- with the diagram of Fe2+ and Fe3+. Can I put them all in one diagram or do I have to make 2?

I hope you can understand my question..
(I am from Switzerland actually and studying in America)

TIA

Offline chehemi123

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Re: soluble Berlin Blue
« Reply #2 on: December 03, 2012, 08:21:26 AM »
Do you know why there are 12 σ electrons of 6 H2O in the Fe[(H2O)6]2+ diagram?

Offline chehemi123

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Re: soluble Berlin Blue
« Reply #3 on: December 04, 2012, 01:21:41 PM »
I hope I am not annoying, but it would be great if you could just have a little look at my idea.

I don't know how to combine the two diagrams of the hexacyanoferrates [Fe(CN)6]4- and [Fe(CN)6]3+...so that we have K[Fe(III)Fe(II)(CN6)].

can anyone help me please?  :-\

Offline chehemi123

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Re: soluble Berlin Blue
« Reply #4 on: December 04, 2012, 01:22:57 PM »
sorry, I forgot the attachment: here it is!

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