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Topic: Weak electrolyte freezing point depression  (Read 5052 times)

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Offline Rutherford

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Weak electrolyte freezing point depression
« on: December 11, 2012, 01:11:44 PM »
Calculate the freezing point depression of an acetic acid solution (c=0.1M, ρ=1.006g/cm3) if Ka=1.75*10-5.

I suppose that it is a water solution, so K=1.86KKg/mol.
For a non-electrolyte the formula is Δt=K*b (b-molality).
For a strong electrolyte: Δt=i*K*b (i is Hoff's factor).
What is the formula for a weak electrolyte?

Offline Arkcon

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Re: Weak electrolyte freezing point depression
« Reply #1 on: December 11, 2012, 03:46:42 PM »
And which do you have when you dissolve acetic acid in water?  Do you have an ionized compound, like HCl?  Or do you have a dissolved molecular compound, like sucrose.  Why did they give you Ka?
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline Rutherford

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Re: Weak electrolyte freezing point depression
« Reply #2 on: December 12, 2012, 06:47:25 AM »
I have both the non-dissociated acetic molecules, and the CH3COO- and H+ ions. How to combine these into one equation, and why did they give the density?

Offline Borek

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Re: Weak electrolyte freezing point depression
« Reply #3 on: December 12, 2012, 07:36:58 AM »
What is the meaning of the Van 't Hoff factor?

How are you going to calculate molality?
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Offline Rutherford

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Re: Weak electrolyte freezing point depression
« Reply #4 on: December 12, 2012, 08:36:47 AM »
I was on the wrong track. If I assume that I have 1dm3 of the solution there is 0.1mol of acetic acid and 1000g of water in it so the molality is 0.1mol/kg.
i=1+α(k-1) where k is the number of ions produced when one molecule dissociates. Therefore i=1+(k-1)*sqrt(Ka/c)=1.013.
Δt=1.013*1.86*0.1=0.188. The right answer is 0.191. I believe its because of the approximation I used for α. Thanks so much.

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