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Topic: Crystallisation migration in copolymers  (Read 2273 times)

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Offline TriffidHunter

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Crystallisation migration in copolymers
« on: December 22, 2012, 04:29:58 PM »
I need some help with this problem...

I've made a range of statistical copolymers of varying ratios (e.g. 1:4,2:3,3:2) and run them through the DSC to gain the crystallisation peaks of each copolymer. Why are the peaks in line with the Fox equation? Surely only Tg would be expected to follow this rule, but this doesn't seem to be the case. The two monomers are of the same family if that helps.

Any references would be greatly appreciated.
« Last Edit: December 22, 2012, 04:50:23 PM by TriffidHunter »

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