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Topic: Ester  (Read 1929 times)

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Offline curiouscat

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Ester
« on: January 01, 2013, 08:52:15 AM »
Is this molecule classified as an ester? Assume the COOH and CHO groups didn't exist.



I've always assumed the R and R' groups in an ester as distinct disjoint.
In this example there's no unique way of assigning R and R', correct?


« Last Edit: January 01, 2013, 09:14:22 AM by curiouscat »

Offline sjb

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Re: Ester
« Reply #1 on: January 01, 2013, 09:09:26 AM »
What do you mean by distinct? Clearly the chain you get if you follow back from the acid part of the RCO2R' group is different from the one that you get if you follow the alcohol. It could be that you may want to class this as a lactone (cyclic ester), but this is clearly still an carboxylic ester.

Offline curiouscat

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Re: Ester
« Reply #2 on: January 01, 2013, 09:13:48 AM »
What do you mean by distinct? Clearly the chain you get if you follow back from the acid part of the RCO2R' group is different from the one that you get if you follow the alcohol.

Right. I ought to have said disjoint.


Quote
. It could be that you may want to class this as a lactone (cyclic ester), but this is clearly still an carboxylic ester.
Right again. Thanks. "Cyclic ester" clarifies it entirely.

Offline OrganicSyn1.0

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Re: Ester
« Reply #3 on: January 02, 2013, 11:19:03 PM »
This is a shoot off question....suppose it was not a lactone but just a straight alkyl chain with a COOH gama to the sp3 oxygen of the ester. What would the nomenclature for this be?

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