The terms molecules and atoms are not interchangeable. C2H6 is a molecule, and it would be incorrect to call it an atom. The ethane molecule, however, is composed of two carbon atoms and six hydrogen atoms. It would also be incorrect to call these carbons or hydrogens molecules. You will occasionally hear people refer to hydrogen molecules, which refers to the molecule H2. Indeed, to distinguish between H and H2, we often call these atomic hydrogen and molecular hydrogen.
With respect to moles, 6.02x1023 atoms is a mole of atoms. 6.02x1023 molecules is a mole of molecules. 6.02x1023 eggs is a mole of eggs. It is simply a quantity, like saying 12 of something is a dozen of something.