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Topic: is this a mistake? Mg(HAsO4)2  (Read 3027 times)

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Offline kriggy

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is this a mistake? Mg(HAsO4)2
« on: May 24, 2013, 02:29:35 PM »
Hi guys,
one of my friends is revising for exams and she asked me: name this compound:
Mg(HAsO4)2
I was like haha its easy before I realized that As is in same group as P so its its As5+ and not As6+.And the acid is H3AsO4
So Im thinking it is just a typo and it should be most likely Mg(HAsO4) or Mg(H2AsO4)2. Anyway, I just want to make sure I´m not mistaken.
Am I? Or are there any Arsenic shenanigans which I´m not aware of.
Thank you

Offline Borek

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Re: is this a mistake? Mg(HAsO4)2
« Reply #1 on: May 24, 2013, 04:43:01 PM »
I would bet on typo. But I don't pretend to know everything about arsenic chemistry.

There is always a slight chance that you are expected to name the compound using systematic approach - IUPAC rules are constructed in such a way it should be possible to name every compound. But I doubt that's the case.
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Offline 9-92-6-19

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Re: is this a mistake? Mg(HAsO4)2
« Reply #2 on: May 24, 2013, 05:54:02 PM »
It could actually be possible; there are some major differences between Phosphorus and Arsenic as oxides. For example, H3PO3 is tetrahedral with two O—H bonds that are acidic, one P—H bond, and a P=O; this is quite unlike H3AsO3 which is trigonal pyramidal and acts with three As—OH bonds.
Of course, I'm not a master at Arsenic chemistry, either.
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