It could actually be possible; there are some major differences between Phosphorus and Arsenic as oxides. For example, H3PO3 is tetrahedral with two O—H bonds that are acidic, one P—H bond, and a P=O; this is quite unlike H3AsO3 which is trigonal pyramidal and acts with three As—OH bonds.
Of course, I'm not a master at Arsenic chemistry, either.