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Topic: rate equation  (Read 2335 times)

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Offline bluepink

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rate equation
« on: February 01, 2009, 10:17:18 AM »
H2(g)+I^2(g) --->2HI(g)
Step 2 is the rate determining step
Thus, Rate = k'[H2(g)][I(g)]2

CAN THE ORDER OF REACTION BE DETERMINED IN THE BALANCED EQUATION?
ISN'T IT NEED TO BE DETERMINED BY DOING THE EXPERIMENT?
I DON'T UNDERSTAND HOW CAN I ACHIEVE THE ABOVE ANSWER.
THX

Offline Astrokel

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Re: rate equation
« Reply #1 on: February 01, 2009, 01:19:39 PM »
Look at the mechanism(slow step) to determine the rate law. The stoichiometric ratio of the reactants in the slowest step is the order of that reactants.

When a mechanism is proposed, you will hope that it tally with your experimently determined rate law.
No matters what results are waiting for us, it's nothing but the DESTINY!!!!!!!!!!!!

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