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Topic: Calculating enthalpies  (Read 2079 times)

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Offline diah

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Calculating enthalpies
« on: October 17, 2013, 03:52:44 PM »
If you're given a reaction, such as;
2O(g)-->O2(g) with delta H=-249 kJ/mol OR
C(graphite)+2H2(g)-->CH4(g) with delta H=-75 kJ/mol

then how do you calculate the heat of combustion of methane into gaseous H2O?

I found the enthalpies of H2O(g) which is -241.8 kJ/mol and CH4 is -74.9 kJ/mol, do you use the equation of delta H=(sum of products)-(sum of reactants) or something else?


Offline Corribus

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Re: Calculating enthalpies
« Reply #1 on: October 17, 2013, 04:39:09 PM »
Always start with a balanced chemical reaction equation.  Which in your case would be.... what do you think?
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline diah

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Re: Calculating enthalpies
« Reply #2 on: October 17, 2013, 05:27:35 PM »
Would you add in O2 and CH4 on the reactant side and then H2O(g) on the product side?

Offline Corribus

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Re: Calculating enthalpies
« Reply #3 on: October 17, 2013, 06:32:12 PM »
You're missing something.  And also, you need to balance the equation.
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline diah

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Re: Calculating enthalpies
« Reply #4 on: October 17, 2013, 08:08:14 PM »
I got 4O(g)+CH4(g)-->2H2O(g)+CO2(g)

What is missing?

Offline Corribus

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Re: Calculating enthalpies
« Reply #5 on: October 18, 2013, 10:52:27 AM »
You must be careful. Methane doesn't react with "O(g)".
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

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