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Topic: Equilibrium #3  (Read 2109 times)

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Offline Cheistrynoob768

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Equilibrium #3
« on: October 19, 2013, 01:25:10 AM »
Question 6: http://imgur.com/4Mz6FBR

My Work: http://imgur.com/wDj6O8y

I just did an ice table and I did some calculations on my calculator based on this work and I got a wrong answer, the answer should be 0.71 mol, I got 0.68 mol...

Offline magician4

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Re: Equilibrium #3
« Reply #1 on: October 19, 2013, 09:41:18 AM »
again, this question can only be answered by setting up a decent LMW expression first:

[tex]K_c = \frac {[CO_2]^2}{[CO]^2 \ \cdot \ [O_2]}[/tex]

what's a given , what are we looking for?

- we start with carbon monoxide, oxygen exclusively: no carbondioxide whatsoever
- therefore, all carbondioxide in equilibrium must have come from carbonmonoxide
- as per one carbondioxide gained one carbon monoxide is lost, it follows: ceq.(CO) = c0(CO) - ceq.(CO2)
- we know the conc. of two of those gases at eq., as we know those moles and the volume that contains them

let's go on by putting numbers in the equation:

[tex]4.2 = \frac {(0.34)^2}{[CO]^2 \ \cdot \ 0.2}[/tex]

this you can resolve for ceq.(CO) , and calculate c0(CO) from that value


... and I agree with approx. 0.71 moles

regards
Ingo

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Offline Cheistrynoob768

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Re: Equilibrium #3
« Reply #2 on: October 20, 2013, 12:33:18 AM »
I tried doing it again but I got a worse answer,

4.2 = 0.34^2 / (y - 0.68)^2 * 0.20

.916515139 = 0.34/y - 0.68

.916515139y - 0.6232302945 = 0.34

y = 1.05 mol/L

1.05 * 1L = 1.05 mol

Offline magician4

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Re: Equilibrium #3
« Reply #3 on: October 20, 2013, 09:09:09 AM »
[tex]c_eq(CO) \neq c_0(CO) - 0.68 [/tex]

that's the source of your error


regards

Ingo
There is a theory which states that if ever anybody discovers exactly what the Universe is for and why it is here, it will instantly disappear and be replaced by something even more bizarre and inexplicable. There is another theory which states that this has already happened.
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